PV diagram

Also called Pressure-volume diagram, Pressure-volume graph

A PV diagram is a graph of a gas's pressure against its volume, with pressure on the vertical axis. Each point is one state of the gas, each curve is one process, and the area under a curve gives the magnitude of the work.

Pressure up the vertical axis, volume along the horizontal one. Essential knowledge 9.4.B.2 calls them pressure-volume graphs, also known as PV diagrams, and describes them as representations of thermodynamic processes.

A point is a state, a curve is a process. Fixing PP and VV fixes the temperature through PV=nRTPV = nRT, and for a monatomic ideal gas it fixes the internal energy as well, since U=32nRT=32PVU = \tfrac{3}{2}nRT = \tfrac{3}{2}PV. The same point always carries the same UU, whatever route the gas took to reach it.

Area is work. 9.4.B.2.ii puts it carefully: the absolute value of the work done on a gas as it expands or compresses equals the area underneath the curve on a plot of pressure against volume. An area is a magnitude and carries no sign, so the sign comes from the direction of travel together with the sheet's W=PΔVW = -P\Delta V, work done on the gas. Move right, the gas expands and WW is negative. Move left, it is compressed and WW is positive. Move straight up or down and the region has no width, so W=0W = 0.

A closed loop encloses the net work in magnitude, because the areas under the outward and return legs overlap and cancel. See cyclic process.

9.4.B.2.i supplies the vocabulary for the curves: a line of constant temperature on a PV diagram is an isotherm.

Reading a particular diagram, assigning signs leg by leg and totalling a cycle is the PV diagrams guide's job.

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